Lithium Nickel Manganese Cobalt Oxide Micron Powder ( LiNiMnCoC, D50: 9.9µm, NMC 111)

Technical Specification:

1. Material Composition:
   • Chemical Formula: LiNi₁/₃Mn₁/₃Co₁/₃O₂ (NMC 111)
   • Metal Ratio: Nickel (Ni): Manganese (Mn): Cobalt (Co) = 1:1:1
   • Purity: ≥99% (battery-grade quality).
2. Particle Properties:
   • Particle Size (D50): 9.9 µm
     • Median particle size ensures uniform distribution and consistent electrochemical performance.
   • Morphology: Spherical or sub-spherical particles with optimized tap density.
3. Physical Properties:
   • Density:
     • Tap Density: ~2.0–2.3 g/cm³
   • Specific Surface Area: ~0.3–0.6 m²/g
     • Balances reactivity and stability.
   • Crystal Structure: Layered α-NaFeO₂ type (R-3m space group).
4. Electrochemical Properties:
   • Average Operating Voltage: ~3.7–3.8 V (vs. Li/Li⁺).
   • Specific Capacity: ~150–160 mAh/g.
   • Cycle Life: Excellent cycling stability under typical lithium-ion battery operating conditions.
5. Thermal Stability:
   • Moderate stability; thermal management required for high-rate applications.
6. Compatibility:
   • Compatible with common liquid electrolytes used in lithium-ion batteries.

Applications:

1. Primary Applications:
   • Cathode Material for Lithium-Ion Batteries (LIBs):
     • NMC 111 is widely used in applications requiring a balance between energy density, safety, and cost.
2. Industries:
   • Electric Vehicles (EVs):
     • Applied in battery packs for EVs, hybrid electric vehicles (HEVs), and plug-in hybrid electric vehicles (PHEVs).
   • Portable Electronics:
     • Powers devices like smartphones, laptops, and wearables.
   • Energy Storage Systems (ESS):
     • Integral in renewable energy storage and grid-level energy solutions.
3. Advantages for Applications:
   • Energy Density:
     • Balanced nickel content ensures high energy storage capacity.
   • Thermal Stability:
     • Manganese enhances safety and thermal performance.
   • Cycle Life:
     • Cobalt contributes to structural stability and prolonged lifespan.
   • Cost-Effectiveness:
     • The balanced composition offers an economical solution compared to cobalt-heavy cathodes.
4. Specialized Uses:
   • Hybrid and Mixed Battery Systems:
     • Used in combination with other cathode materials to tailor performance for specific applications.
   • High-Performance Batteries:
     • Suitable for applications requiring long cycle life and consistent performance, such as medical devices and aerospace systems.
5. Challenges and Mitigation:
   • Thermal Management:
     • Requires effective heat dissipation systems in high-rate charging/discharging applications.
       • Solution: Pair with optimized electrolyte and thermal control systems.
   • Nickel Content Sensitivity:
     • Slight degradation may occur under extreme cycling conditions.
       • Solution: Enhance with coatings or additives to stabilize the material.

Summary:

Lithium Nickel Manganese Cobalt Oxide Micron Powder (NMC 111) is a widely used cathode material offering a balanced performance profile of energy density, thermal stability, and cycle life. With a D50 of 9.9 µm and a uniform particle morphology, it is optimized for lithium-ion battery applications in electric vehicles, portable electronics, and energy storage systems. NMC 111 remains a popular choice for its cost-effectiveness and versatility, making it a critical material in the evolving energy storage landscape.